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    Home News Product Information Development of Silicones in the Personal Care Field and Core Information on Silicone Cross-Linked Polymers

    Development of Silicones in the Personal Care Field and Core Information on Silicone Cross-Linked Polymers

    author: Leo
    2025-09-19
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    I. Development History of Silicone Oil in the Personal Care Field

    • 1950: Low-viscosity silicone oil was used in skin care products to play a role in lubrication and care;
    • 1970: Volatile silicone oil was used in antiperspirants as a volatile carrier, which left no residue on the skin and provided a light skin feel;
    • 1980: High-viscosity silicone oil was used in shampoos and conditioners to deliver a silky and smooth hair texture;
    • 1990: Various modified silicone oils such as amino silicone oil and polyether silicone oil were applied in shampoos, conditioners, hair treatments, and hair gels, enriching the formula options;
    • 2000: Silicone resins and silicone elastomers were used in color cosmetics and skin care products, bringing the product formulas to a brand-new sensory level defined as "silky".

    II. Core Information on Silicone Cross-Linked Polymers

    1. Initial Form

    It initially existed in the form of gel. Due to its ability to bring light, silky, easy-to-spread, dry and non-greasy skin feel to cosmetics, it has been widely recognized by formulators.

    2. Structure

    Silicone cross-linked polymer gel is a mixture of high-molecular-weight siloxane cross-linked polymers dispersed in volatile cyclic siloxanes, low-viscosity silicone oils, or organic oils. It is prepared by the addition cross-linking of linear polysiloxanes with Si—H groups in the side chains and vinyl-terminated polysiloxanes in a solvent.

    3. Classification

    • By cross-linked polymer structure: To improve compatibility with various personal care ingredients, organic functional groups such as alkyl, polyether, and amino groups are grafted onto the main chain of cross-linked polysiloxanes. It is classified into methyl vinyl silicone cross-linked polymer, methyl polyether silicone cross-linked polymer, long-chain alkyl vinyl silicone cross-linked polymer, polyether long-chain alkyl silicone cross-linked polymer, etc.;
    • By appearance form: Starting from the initial gel, it has developed into various forms such as powder mixtures, emulsions, suspensions, and composite powders.

    4. Characteristics and Values

    • Skin feel advantages: It can endow products with a dry, silky, and light skin feel;
    • Additional functions: It absorbs oil and improves aesthetic effects (e.g., soft focus, covering wrinkles and skin blemishes);
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